Download e-book for kindle: Advances in Organobromine Chemistry II: Proceedings Orgabrom by Desmurs J.-R., Gerard B., Goldstein M.J.

By Desmurs J.-R., Gerard B., Goldstein M.J.

ISBN-10: 0444821058

ISBN-13: 9780444821058

The natural molecules which are used, rather within the components of pharmacy and agrochemicals, have gotten progressively more complicated either of their chemical nature and spacial configuration. a posh molecular constitution is necessarily fragile; it can't be produced lower than serious stipulations (in specific excessive strain and temperature). furthermore there's a challenge of the scale-up of a product from the laboratory to the economic scale. The keep watch over of the reactivity, selectivity, and yield and using sufficiently gentle business stipulations are all components that has to be taken into consideration by way of business chemists. among the ''tools'' giving controllable reactivity, selectivity, and comparatively light response stipulations is bromine. The natural chemistry of bromine occasionally provides incredible selectivities in comparison to these of chlorine. This quantity that's in accordance with ''Orgabrom '93'', brings jointly the most contributions offered at this occasion.

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Additional info for Advances in Organobromine Chemistry II: Proceedings Orgabrom '93, Jerusalem, June 28-July 2, 1993

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7)(ref. 8). ~~'-CH2Me3NC1 (AGI-X 2) NaOH / H20 HBr / H20 v (PH = 13) (PH = 1) Br 2 )--CHzMe3NBr (~ CH2Me3NBr CHEC12 = styrene polymer Fig. 6. Preparation of styrene polymer-bound BTMA Br3 Br 2, CH 2C12 ~ ' ~ CH2Me3NBr 3 orange red ~-- HO CH2Me3NBr + + Brn colorless n HBr colorless [ Fig. 7. Bromination of phenols with styrene polymer-bound BTMA Br3 Recently, Smith et al. reported that the reaction of phenols with a calculated amount of the polymer-bound BTMA Br 3 gave p-monobromo-substituted phenols, selectively (ref.

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Advances in Organobromine Chemistry II: Proceedings Orgabrom '93, Jerusalem, June 28-July 2, 1993 by Desmurs J.-R., Gerard B., Goldstein M.J.


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